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Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels, Sun
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Автор:
Sun
Название:
Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels
ISBN:
9789819945092
Издательство:
Springer
Классификация:
Спектральный анализ, спектрохимия, масс-спектрометрия
Физическая химия
Машиноведение
Прочие технологии и прикладные науки
ISBN-10: 9819945097
Обложка/Формат: Hardback
Страницы: 168
Вес: 0.00 кг.
Дата издания: 05.09.2023
Серия: Springer theses
Язык: English
Издание: 1st ed. 2023
Иллюстрации: 100 illustrations, color; 41 illustrations, black and white; xv, 168 p. 141 illus., 100 illus. in color.
Размер: 235 x 155
Основная тема: Materials Science
Ссылка на Издательство:
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Поставляется из: Германии
Описание: In this thesis, attention was paid to several novel oxygenated fuels—carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed. On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.
Дополнительное описание: Introduction.- Experimental and kinetic modeling methods.- High-temperature kinetics of carbonate and ketone fuels.- Low-temperature oxidation kinetics of polyether fuels.- Addition effects of oxygenated fuels on hydrocarbon premixed flames.- Conclusions
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