Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface.
Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.
Автор: Efstathios E. (Stathis) Michaelides Название: Nanofluidics ISBN: 3319056204 ISBN-13(EAN): 9783319056203 Издательство: Springer Рейтинг: Цена: 19377.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Nanofluidics
Автор: Hutter Название: Fluid and Thermodynamics ISBN: 3319336355 ISBN-13(EAN): 9783319336350 Издательство: Springer Рейтинг: Цена: 22797.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: In this book fluid mechanics and thermodynamics (F&T) are approached as interwoven, not disjoint fields. The book starts by analyzing the creeping motion around spheres at rest: Stokes flows, the Oseen correction and the Lagerstrom-Kaplun expansion theories are presented, as is the homotopy analysis. 3D creeping flows and rapid granular avalanches are treated in the context of the shallow flow approximation, and it is demonstrated that uniqueness and stability deliver a natural transition to turbulence modeling at the zero, first order closure level. The difference-quotient turbulence model (DQTM) closure scheme reveals the importance of the turbulent closure schemes’ non-locality effects. Thermodynamics is presented in the form of the first and second laws, and irreversibility is expressed in terms of an entropy balance. Explicit expressions for constitutive postulates are in conformity with the dissipation inequality. Gas dynamics offer a first application of combined F&T. The book is rounded out by a chapter on dimensional analysis, similitude, and physical experiments.
A large amount of experimental data has been published since the debut of the original CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions. Incorporating new and updated material, the CRC Handbook of Phase Equilibria and Thermodynamic Data of Aqueous Polymer Solutions provides a comprehensive collection of thermodynamic data of polymer solutions. It helps readers quickly retrieve necessary information from the literature, and assists researchers in planning new measurements where data are missing.
A valuable resource for the modern chemistry field, the Handbook clearly details how measurements were conducted and methodically explains the nomenclature. It presents data essential for the production and use of polymers as well as for understanding the physical behavior and intermolecular interactions in polymer solutions.
Автор: Wohlfarth, Christian Название: CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions ISBN: 0849321743 ISBN-13(EAN): 9780849321740 Издательство: Taylor&Francis Рейтинг: Цена: 59717.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Автор: Lee Lloyd L. Название: Molecular Thermodynamics of Electrolyte Solutions: Second Edition ISBN: 9811232997 ISBN-13(EAN): 9789811232992 Издательство: World Scientific Publishing Рейтинг: Цена: 19008.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-H ckel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications -- natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
Автор: Lee Lloyd L. Название: Molecular Thermodynamics of Electrolyte Solutions: Second Edition ISBN: 9811234175 ISBN-13(EAN): 9789811234170 Издательство: World Scientific Publishing Рейтинг: Цена: 11088.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-H ckel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications -- natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
Автор: Jose Casas-Vazquez; David Jou Название: Rheological Modelling: Thermodynamical and Statistical Approaches ISBN: 3662138689 ISBN-13(EAN): 9783662138687 Издательство: Springer Рейтинг: Цена: 13677.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The pedagogically presented lectures deal with viscoelastic behaviour of fluids, the compatibility of rheological theories with nonequilibrium thermodynamics, fluids under shear, and polymer behaviour in solution and in biological systems.
Автор: Felix Franks Название: Aqueous Solutions of Simple Electrolytes ISBN: 1468429574 ISBN-13(EAN): 9781468429572 Издательство: Springer Рейтинг: Цена: 12537.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions.
Автор: Wohlfarth, Christian Название: CRC Handbook of Thermodynamic Data of Copolymer Solutions ISBN: 0849310741 ISBN-13(EAN): 9780849310744 Издательство: Taylor&Francis Рейтинг: Цена: 59717.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Ten years after the debut of the expansive CRC Handbook of Thermodynamic Data of Copolymer Solutions, The CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions updates and expands the world's first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the CRC Handbook of Chemistry and Physics, has gathered up-to-the-minute data from more than 500 newly published references. Fully committed to ensuring the reliability of the data, the author included only results with published or personally communicated numerical values.
With volumetric, calormetric, and various phase equilibrium data on more than 450 copolymers and 130 solvents, this handbook furnishes:
150 new vapor-liquid equilibrium datasets
50 new tables containing classical Henry's coefficients
250 new liquid-liquid equilibrium datasets
350 new high-pressure fluid phase equilibrium
70 new PVT-properties datasets
40 new enthalpic datasets
Expanded second osmotic virial coefficients data table
Carefully organized, clearly presented, and fully referenced, The Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions will prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers.
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